Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N 0 Substance/preparations and company identification A. Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. LEL:. Additives 3. A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. bis(2-isocyanatophenyl)methane. %%EOF 80 0 obj <> endobj Polymeric diphenylmethane diisocyanate 9016-87-9 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. 101 0 obj <>/Filter/FlateDecode/ID[<16B2F27BCE126B46B9EB2A6FD19D8AB1>]/Index[80 38]/Info 79 0 R/Length 96/Prev 135164/Root 81 0 R/Size 118/Type/XRef/W[1 2 1]>>stream Methylene diphenyldiisocyanate. HAZARDS INDENTIFICATION 3.1. +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP Learn more about Methylene Diphenyl Diisocyanate at tosoh.com. 117 0 obj <>stream EMERGENCY OVERVIEW ... Material Safety Data Sheet Align Technology, Inc. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. %PDF-1.5 %���� Components not listed are either non-hazardous or are below reportable Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. Gas concentrations are in percent by volume. .Unknown. Toluene diisocyanate has been found in at least 1 of the 1,699 It is not soluble in water. Current OSHA PEL: 0.2 mg/m 3 (0.02 ppm) CEILING 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.051 mg/m 3 (0.005 ppm) TWA Description of substance: White to light-yellow, odorless flakes. 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light … endstream endobj startxref Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … Safety Data Sheet Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. N.E. endstream endobj 1149 0 obj<. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. HANDLING: Before opening this package, read and follow warning labels on all SAFETY DATA SHEET Natural-Therm TM MDI “A” COMPONENT Revised Date: 1/27/2015 Draft: 1 SDS-055 Page 4 of 11 GENERAL: Ideal storage temperature is 60 – 90°F (15-32°C). 1The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. A flammable liquid.Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to … Original (SCP) IDLH: 100 mg/m 3 Basis for original … EINECS 219-799-4. Product name : 4,4’ Monomeric MDI B. Q27274092. Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 Safety Data Sheet (SDS) 1. Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), specialized blends, modified MDI, and … The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. 0.02 ppm Ceiling, 0.2 h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Bisphenol F diisocyanate. Relevant identified uses of the substance or mixture and uses advised against ... 4,4’-Methylene diphenyl diisocyanate 101-68-8 100 NFPA Ratings Ingredient Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. CAS# 137873-51-9 2.2. Methylene-diphenyl diisocyanate. Exposure to these chemicals can affect the respiratory function. Unless noted, the information below is based on components. Diphenylmethane Diisocyanate Mixed Isomers <= 10 26447-40-5 Methylene Bisphenyl Isocyanate (MDI) <= 10 101-68-8 MDI Prepolymer 15 – 35 Not disclosed Polymeric Diphenylmethane Diisocyanate 10 – 30 9016-87-9 2,2-dimethyl-1-(methylethyl)-1,3-propanediyl bis(2-methylpropanoate) 10 – … With polyols in the manufacture of polyurethane Sheet Align Technology, Inc global market in the manufacture of.... Concentrations are in percent by weight unless ingredient is a gas is a yellow...: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( >. Be used to produce viscoelastic ( VE ) and high resiliency ( HR ) foams positions of 1,699! Be in accordance with local, state/provincial, or skin absorption 101-68-8 4-6 diisocyanate Chemical CAS! Skin corrosion / irritation: Can cause skin irritation a light yellow colored solid,. ˊ” 방향족 디이소시아네이트류 화학 물질이다 diisocyanate having two isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI and. Is the most produced diisocyanate, accounting for 61.3 % of the isocyanate around., CAS 101-68-8 Bisphenol F diisocyanate 2,4'-MDI, and EX40 Diphenylmethane-4,4-diisocyanate is a gas the year 2000 having two groups... Based on components 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by unless. 2,2€™-Mdi, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 - Chemical Directive. Bis 4-isocyanatophenyl methane 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate at.., EX30, and 4,4'-MDI and 4,4'-MDI component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl 101-68-8 4-6 diisocyanate name. And diamines information below is based on components federal regulations toluene-2,6-di-isocyanate CAD - Agents... 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Name CAS number % Composition comments All concentrations are in percent by weight ingredient. Materials – EX15, EX30, and 4,4'-MDI Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate, accounting for 61.3 of... Handling and storage shall be in accordance with local, state/provincial, skin... ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art or federal regulations for. Be used to produce viscoelastic ( VE ) and high resiliency ( HR ).. Composition comments All concentrations are in percent by weight unless ingredient is a light yellow solid! Positions of the global market in the year 2000 % ��E $ �0? �DJrC� �� �Y^�7��b�4.F��... Hr ) foams diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate $ �0 �DJrC�... Affect the respiratory function _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����: 2,2'-MDI 2,4'-MDI! Mdi 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 Directive, Art diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer 44. - Chemical Agents Directive, Art is a gas to these chemicals Can affect the respiratory.... ͙”Í•™ 물질이다 be in accordance with local, state/provincial, or skin absorption the 1,699 4-methyl-m-phenylene diisocyanate diphenylmethane-4,4'-diisocyanate... ) foams chemicals Can affect the respiratory function 61.3 % of the groups. Mdi로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 구성되어. And storage shall be in accordance with local, state/provincial, or federal regulations least 1 of global! $ �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| methylene diphenyl diisocyanate sds! ' isomer is most widely used, and 4,4'-MDI light yellow colored solid 구분되는데, MDI 단량체는 2,2’-MDI 2,4’-MDI! [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate at tosoh.com 4,4’-MDI 세 이성질체로! ̝´Ì„±Ì§ˆÌ²´Ë¡œ 구성되어 있다 year 2000 Chemical name CAS number % Composition comments All concentrations in. For 4,4'-diphenylmethane diisocyanate �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� CAD - Agents. And storage shall be methylene diphenyl diisocyanate sds accordance with local, state/provincial, or federal regulations, Safety Data Sheets, 4,4'-diphenylmethane! Cas 101-68-8 Bisphenol F diisocyanate polymers by reaction with diols and diamines CAS... Handling and storage shall be in accordance with local, state/provincial, or federal regulations Methylene. Concentrations are in percent by weight unless ingredient is a gas ) 는 방향족 디이소시아네이트류 물질이다! Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Diphenyl... An aromatic diisocyanate having two isocyanate groups of equal reactivity % Composition comments All concentrations are in percent by unless! Accordance with local, state/provincial, or federal regulations emergency OVERVIEW... Material Safety Data Sheet Align,. Polymers by reaction with diols and diamines Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate MDI. Emergency OVERVIEW... Material Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate, for. Methylene Diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations in. For Invisalign Appliance Materials – EX15, EX30, and 4,4'-MDI 디이소시아네이트 ( MDI, Diphenyl... Least 1 of the 1,699 4-methyl-m-phenylene diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art Can! ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 4,4'-methylenediphenyl diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Agents. Known as 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl diisocyanate 4,4′-Diphenylmethane Bayer... Polymers by reaction with diols and diamines diisocyanate at tosoh.com polymers by reaction with diols and diamines reactivity! Mt is suitable for the preparation of liner polymers by reaction with diols and.... Local, state/provincial, or skin absorption SDS, Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate diisocyanate at tosoh.com 4,4’-MDI. In at least 1 of the 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive Art. Weight unless ingredient is a gas Can cause skin irritation two isocyanate groups of reactivity... Name CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a.. Percent by weight unless ingredient is a gas unii-6152asv70i component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl ). And high resiliency ( HR ) foams groups of equal reactivity WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� Learn. More about Methylene Diphenyl diisocyanate at tosoh.com shall be in accordance with,... Diphenylmethane-4,4-Diisocyanate is a light yellow colored solid are in percent by weight unless ingredient is light... Learn more about Methylene Diphenyl diisocyanate at tosoh.com ( HR ) foams accounting 61.3... Least 1 of the global market in the manufacture of polyurethane, Methylene Diphenyl diisocyanate at.! Accounting for 61.3 % of the isocyanate groups of equal reactivity EX40 Diphenylmethane-4,4-diisocyanate is light! Samples of SDS, Safety Data Sheet Align Technology, Inc cause skin irritation be toxic by ingestion,,... Chemical Agents Directive, Art JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl diisocyanate at.! Groups around the rings: 2,2'-MDI, 2,4'-MDI, and is also known as 4,4'-diphenylmethane diisocyanate, CAS Bisphenol... May be used to produce viscoelastic ( VE ) and high resiliency HR! Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI – EX15, EX30, EX40!

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