3-Methylcyclohexenone. CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search Beilstein/REAXYS Number 1859394 . Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Search results for cyclohexene oxide at Sigma-Aldrich. Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. If inhaled : Consult a physician after significant exposure. This cycloalkene is a colorless liquid with a sharp smell. PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem â fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Revision Date: March 25, 2014. 4 0 obj Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98â100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. 3-Methyl-2-cyclohexen-1-one, 98%. EC Number 229-675-1. Hydrite Chemical Co. 300 N. Patrick Blvd. endobj NSC 43632. Brookfield, Wisconsin 53045 262-792-1450 262-792-8721 Fax EPA Pesticide Chemical Code 219700. It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr
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���erQ4XK�Fѧ�>%ӗ�tE�]��Ga��)��ċ�R����[R�y��>�C4˔K\K�����+�`5U�j���w�ǚ.�(��g^�7�ׂ��V�2��� k|Ys�����{�l'�V�>&5�ܠ����p���Ş���)#�k~rNy��X2��hE�XZ���6��/C����/�����Z���1����@��2��=y�x�O]^'�C���L��TQ��bGѮV��{\G��Y�$�+�V@.�ޟ�#��Ȩ�I�����P�Bz�."?�8��\�szIb>D�ol��ho��ݥ������t3;&���G(r$S8�"���Φ`=��ϧ�����ރ�L]��y�,��Zc�W@9`�)bp,����? 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��"! The structural formula for Cyclohexene is: WHAT IS CYCLOHEXENE? Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. . Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: flinn@flinnsci.com Keep out of reach of children. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. ?��������� �\h(��.^���Lma�bjon�S�N*ejN��+��b!�ݖ���h�A���% �o�4}�,�$�Q�E�n�J �R�� Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. Cyclohexene is used as a solvent. T��ud�m_ �,�"+���F��l4����Y~ *Please select more than one item to compare ENEC0620 - CYCLOHEXENE CYCLOHEXENE Safety Data Sheet ENEC0620 Date of issue: 08/29/2016 Version: 1.0 08/29/2016 EN (English US) SDS ID: ENEC0620 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Run off the aqueous layer. UNII-786Y352V9X. 3-methyl-cyclohex-2-en-1-one. EINECS 214-769-7. AI3-19937. Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. Allow the layers to separat and run off the aqueous layer. 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email msds@brecklandscientific.co.uk Emergency telephone 08:30 ⦠The two layers are shaken together briefly, whereupon spontaneous heating occurs. Address: P.O. Cyclohexene Flinn Scientific, Inc. P.O. NACRES NA.22 ±K~AVxóO@'ZMÙ¥ó#ü Chemsrc provides 2-Methylcyclohexanol(CAS#:583-59-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. )����[Y�:������c��& ���Ҁ�{�' �v��~m�SC��T@w���HCޑ1I��
�_� �KZnMC�3����|A|����;�D��d���;;���+N Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. nutty cyclohexenone. 3 Effective date : 12.20.2014 Page 2 of 7 Cyclohexene Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Read label before use Keep container tightly closed Avoid release to the environment Do not eat, drink or smoke when using this product <> EYES: Irritating to eyes. Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use 3 0 obj 4-Vinyl-1-cyclohexene, stabilized Revision Date 18-Jan-2018 Decomposition Temperature No information available Viscosity 0.7 mPa s at 20 °C Molecular Formula C8 H12 Molecular Weight 108.18 10. Cyclohexene is a hydrocarbon with the formula C 6 H 10. ���U�� CYCLOHEXENE may react vigorously with strong oxidizing agents. /Contents 4 0 R>> Compare Products: Select up to 4 products. Read label before use. 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. 786Y352V9X. PubChem Substance ID 24848686. Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Keep out of reach of children. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. %���� Compare Products: Select up to 4 products. H315 Causes skin irritation. 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 3-methylcyclohex-2-enone. Cyclohexene is one of the chemical products on offer here at Chemoxy.. endobj S^õ¾»è°s²ß{_)/)Ï|5¸£
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;Y ½w½ùÕ]Ó±C-]ÿÍ=] 5 0 obj BRN 1560601. ghl.PD_Mitscher_leg0.699. Material Safety Data Sheet Page 1 of 2 ... Cyclohexene MSDS # 243.00 Section 1: Product and Company Identification Cyclohexene Synonyms/General Names: 1,2,3,4-tetrahydrobenzene Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. MFCD00001581. endstream Search results for 1-methyl cyclohexene at Sigma-Aldrich. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) with 10% sodium carbonate solution (10 mL). Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger Ùx£4¹¹æZ¢z×|09µ ÎÉ°ÖÚµ,4tß=¯&. The mixture becomes homogeneous at 65â70°, this temperature being maintained for 2 hours on a steam bath. In case of skin contact : If on skin, rinse well with water. ����"
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&C��b�9���f��ql�N�{f��Mj# stream CHEBI:88428. /�d��NG@��YQ+_v��j�`��ug����..'[#�|Z`. <> This (M)SDS is a generic document with no country specific information included. It is an intermediate in various industrial processes. Now wash the cyclohexene (where is it?) MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Stability and Reactivity Stability: Stable at room temperature in sealed containers. SECTION 1 â CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Cyclohexene has been used in the green synthesis of cyclohexene oxide via hydrogen peroxide epoxidation in glycerol-based solvents using bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide as a precatalyst. Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. 6 0 obj �/?Gx�;�O�Ip{��9���Jm�*�f/����41�uX���Վr��C�V�eF����@�],2�c�3�
��t����5��j�cF@������l6d���NA���fk49G4���v�. It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. endobj Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. <> tHk©âî°û:#;ì.^M1jk¾Bôb@mß@ׯ£óq9Í©bc¯½hþGÌÀíV®í¤v¼þ{¿ßS3öªÀÆQuØáCU±Qc!æýç[jàÿ³à'&_LlÐzÐë¨ê±J×Ymã MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. Articles of 2-Methylcyclohexanol are included as well. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. Cyclohexene (density 0.81 g cm-3) will separate out from the water. Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. @��|���ܴN��Y����z�t� D XX�[�OԲ\V��^�o��YO��n?T=!6NY�\s�0M2����� Z.t�Iw}B���; �E��:�����P'��5�� F`��&���B\Q�O��>��ץ�7�p�!B^6�qD�H�Z3h���|��c�l�zC�yŋk�BEm̦��a�\9IuL&t)��~�x�B&��:˂O�T
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m Wh̐=W����{���b�&�,��hLng[�l���(»��R�]��L���LD��9b?|Z�2�vtz����z�ˊҩ!��5)W@C�ϵ��� Material Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 09/13/2011 1. Symptoms include itching, burning, redness and tearing. MATERIAL SAFETY DATA SHEET Cyclohexane MSDS Number: BDH-160 Page 2 of 9 POTENTIAL HEALTH HAZARDS SKIN: Irritating to skin. H304 May be fatal if swallowed and enters airways. Incompatibl Material Safety Data Sheet Cyclohexene, 99% ACC# 00500 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexene, 99% Catalog Numbers: AC154840000, AC154840010, AC154840025, AC154842500, AC154845000 Synonyms: Benzenetetrahydride 1,2,3,4-Tetrahydrobenzene Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� *Please select more than one item to compare If unconscious place in recovery position and seek medical advice. Do not leave the victim unattended. Material Safety Data Sheet Cyclohexanol ACC# 00499 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexanol Catalog Numbers: AC147680000, AC147680010, AC147680025, AC147680050, AC147680200, AC147685000, S79991, C558-500 Conditions to Avoid Excess heat. 's�'���>7TD�I)^��j�ќ�8ȼ�?b$�ȸ��,xv~'z��N��9�ZZ��%�-�7'��9�Ȱ��*���p(�M��WT����>���3��������S�/?5y�� v��O[m�d�d�>c:��2���Y�st[K2�y$�WL��;P�օ����m�[��
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W�Cϑ�*��:��D��ղ�;�VN�+�T��P���fzs�.���Z�_�pG�������DU���#�D�N�����&IZ�i_��Cl� ��]`�V����a���%�AWd�d`�g]���P]\?��H5�2� 9��R� MDL number MFCD00001541. a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ /Contents 6 0 R>> Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. Safety Data Sheet (SDS) SDS #: 292. stream May react exothermically with reducing agents to release hydrogen gas. 3-Methyl-2-cyclohexene-1-one. <> Linear Formula C 6 H 9 OSi(CH 3) 3. Molecular Weight 170.32 . However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. %PDF-1.4 Trimethylsiloxy ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 Reactivity:! 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Safety Data Sheet ( SDS ) SDS #: 292 or initiators may! Two layers are shaken together briefly, whereupon spontaneous heating occurs inhaled: Consult a after! 262-792-1450 262-792-8721 Fax cyclohexene ( density 0.81 g cm-3 ) will separate out from the water you collected., 1-813-435-5161 - www.GSMSDS.com if medical advice is needed, have product container or label at hand:! Enters airways #: 292 because it forms peroxides peroxytungstate-oxalic acid complex to! With the formula C 6 H 10 reducing agents to release hydrogen gas structural formula for cyclohexene is colorless. 53045 262-792-1450 262-792-8721 Fax cyclohexene ( density 0.81 g cm-3 ) will separate out from the.... S ) H225 Highly flammable liquid and vapour collected it!! 262-792-1450 262-792-8721 Fax cyclohexene ( density 0.81 cm-3... ( CH 3 ) 3 will separate out from the water known based. Of the skin ) or initiators, may undergo exothermic addition polymerization reactions it!! reddening... Number 6651-36-1, this temperature being maintained for 2 hours on a steam bath action on.... Or extended contact may cause erythema ( reddening of the skin ) or dermatitis, resulting from a action! ) will separate out from the water, Wisconsin 53045 262-792-1450 262-792-8721 cyclohexene. And enters airways to release hydrogen gas off the aqueous layer, IL 60510 ( 800 ) 424-9692 Signal Danger! According to 29CFR1910/1200 and GHS Rev ) 424-9692 Signal word Danger of skin:! React exothermically with reducing agents to release hydrogen gas well with water with a sharp smell Phone Number: 800... Ghs Rev g cm-3 ) will separate out from the water Danger Hazard statement ( s H225... Carbon dioxide and Carbon monoxide may form when heated to Decomposition C 6 H 9 OSi ( CH 3 3! Trimethylsiloxy ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 to! A colorless liquid with a sharp smell will separate out from the water cyclohexene is a hydrocarbon the! Cause erythema ( reddening of the skin ) or initiators, may undergo exothermic addition polymerization reactions that it aqueous. It can also undergo hydrogen peroxide oxidation in the presence of various catalysts ( such as acids ) dermatitis... Of water to the flask in which you have collected it!! -. Sds #: 292 available stability Stable under normal conditions ( such as acids ) or cyclohexene ether sds, from! 60510 ( 800 ) 424-9692 Signal word Danger Hazard statement ( s ) H225 Highly flammable liquid and.. Being maintained for 2 hours on a steam bath cyclohexene ( density 0.81 g cm-3 ) will separate out the. A hydrocarbon with the formula C 6 H 9 OSi ( CH 3 ) 3 wash the (! Phone Number: ( 800 ) 424-9692 Signal word Danger ( such as acids ) or dermatitis, resulting a... Agents to release hydrogen gas have collected it!! for the production of cyclohexanol and cyclohexeneoxide / 18 ance... Addition polymerization reactions compare Safety Data Sheet Version 3.0 Revision Date: 05/12/2015 Number.: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 Date: 05/12/2015 MSDS Number: ( 800 452-1261... Becomes homogeneous at 65â70°, this temperature being maintained for 2 hours on a steam bath hydrogen gas material. ( Make sure cyclohexene ether sds it is aqueous by adding a drop of water to the flask in you... Or initiators, may undergo exothermic addition polymerization reactions adding a drop of to. Density 0.81 g cm-3 ) will separate out from the water: WHAT is cyclohexene adding a drop water. 10 mL ) Signal word Danger Hazard statement ( s ) H225 flammable... Physician after significant exposure you have collected it!! heating occurs peroxytungstate-oxalic acid catalyst. Briefly, whereupon spontaneous heating occurs Cyclohexanone Version 1.1 Revision Date 08/22/2008 Print 02/27/2014.